Nope! Both are fully native macOS apps, at least on the version of Monterey that I'm running.
You can examine which frameworks a binary links by running `otool -l /System/Applications/Photos.app/Contents/MacOS/Photos`. Traditional macOS Cocoa apps will link AppKit, while Catalyst apps will link UIKit.
For example, if you run that command with a Catalyst app (e.g., Messages or Maps), you'll see that those apps link against `/System/iOSSupport/System/Library/Frameworks/UIKit.framework/Versions/A/UIKit`, and AppKit is nowhere to be found.