They are called "fossil fuels" to distinguish whether their combustion increases the amount of CO2 in the atmosphere (on timescales less than tens of thousands of years). That's a pretty important distinction to keep track of...
Yeah. About the only thing you don't get from ethanol compared to hydrocarbons is... volatile hydrocarbons, and of course (unsunk) CO2.
The combustion outputs are quantitatively different, but the same compounds are present. Whether ethanol produces cleaner combustion products compared to gasoline is debated in the literature.
Of course, when it comes to particulates, things like diesel or bunker oil are much worse than either gasoline or ethanol.
If I burn plant derived ethanol the same hazards exist.
The term "fossil fuel" should be made obsolete.